Sr3B14O24: a new borate with a [B14O30] fundamental building block and an unwonted 2D double layer

Abstract

A new alkaline-earth metal borate, Sr₃B₁₄O₂₄, was successfully synthesized by a high-temperature solution method. It crystallizes in the monoclinic space group P2₁/c (no. 14) and features a fundamental building block (FBB) [B₁₄O₃₀] which is composed of eight [BO₃] and six [BO₄] units. The FBBs further condense to form an unwonted infinite 2D double layer extended in the bc plane. The UV-Vis-NIR diffuse reflectance spectrum shows that the cutoff edge of Sr₃B₁₄O₂₄ is less than 200 nm, which indicates its potential use in the deep UV region. In addition, the first principles theoretical study was carried out to better understand the relationship between the structure and performance.