Cooperative B–H activation by Cp* based κ2-N,S-chelated Ru(ii) and Mo(ii) complexes (Cp* = η5-C5Me5)

Abstract

The chemistry of the Cp* based κ²-N,S-chelated ruthenium complex, [Cp*RuPPh₃(κ²-N,S-(NC₇H₄S₂)], 1 with different boranes has been explored. The room temperature reaction of 1 with BH₃·THF and bulky boranes, such as MesBH₂ and H₂BAr^F, led to the formation of different dihydridoborate complexes, [{κ³-S,H,H-(NBH₂R)(S₂H₄C₇)}RuCp*], 2–4 (2: R = H, 3: R = Mes, and 4: R = Ar^F; Mes = 2,4,6-trimethylphenyl, and Ar^F = 3,5-bistrifluoromethyl-benzene). In contrast, the Cp* based κ²-N,S-chelated molybdenum complex, [Cp*Mo(CO)₂{κ²-N,S-(NC₇H₄S₂)}], 5, yielded the agostic borate species, [Cp*Mo(CO)₂{κ²-S,H-(NBH₂R) (NC₇H₄S₂)}], 6 and 7 (6: R = Mes and 7: R = Ar^F) at elevated temperatures.