This work presents a straightforward method for the preparation of an isoindoline bridged [M(arene)2]+ (M = Re, 99mTc) ansa-[3]arenophane. This intramolecular formation of an ansa-complex is accompanied by the intermolecular formation of a pair of isoindoline bridged macrocyclic dinuclear sandwich complexes, one of which exhibits axial chirality.
![Graphical abstract: An isoindoline bridged [M(η6-arene)2]+ (M = Re, 99mTc) ansa-arenophane and its dinuclear macrocycles with axial chirality](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=D2DT00743F&imageInfo.ImageIdentifier.Year=2022)
J. Csucker, D. K. Jo, Q. Nadeem, O. Blacque, T. Fox, H. Braband and R. Alberto, Dalton Trans., 2022, 51, 9591 DOI: 10.1039/D2DT00743F
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