Issue 35, 2022

Immobilization of a trimeric ruthenium cluster in mesoporous chromium terephthalate and its catalytic application

Abstract

Molecular trimeric ruthenium carboxylate clusters (Ru3 clusters) have been introduced into the pore channels of mesoporous metal–organic framework chromium terephthalate [MIL-101(Cr)] by employing a facile two-step post-synthetic strategy in which diamine hooks anchored on the framework metal nodes of the MOF are used to covalently immobilize the Ru3 clusters. The catalytic activity of the isolated Ru3 clusters in the pore channels of the MOF was significantly improved compared to the bulk counterpart.

Graphical abstract: Immobilization of a trimeric ruthenium cluster in mesoporous chromium terephthalate and its catalytic application

Supplementary files

Article information

Article type
Communication
Submitted
11 May 2022
Accepted
03 Aug 2022
First published
04 Aug 2022

Dalton Trans., 2022,51, 13189-13194

Immobilization of a trimeric ruthenium cluster in mesoporous chromium terephthalate and its catalytic application

S. E. Sivan, K. Oh, J. Yoon, C. Yoo and Y. K. Hwang, Dalton Trans., 2022, 51, 13189 DOI: 10.1039/D2DT01462A

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