Two new SmII-azacryptates are reported that differ in steric hindrance and Lewis basicity of donor atoms. The sterically hindered complex has a smaller coordination number and a more negative electrochemical potential than the complex with less steric hindrance.
![Graphical abstract: Solid-state and solution-phase characterization of SmII-aza[2.2.2]cryptate and its methylated analogue](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=D2DT01823C&imageInfo.ImageIdentifier.Year=2022)
S. S. Bokouende, T. C. Jenks, C. L. Ward and M. J. Allen, Dalton Trans., 2022, 51, 10852 DOI: 10.1039/D2DT01823C
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