Design of “turn-off” luminescent Ln-MOFs for sensitive detection of cyanide anions

Abstract

Two novel 2D lanthanide metal–organic frameworks (Ln-MOFs), namely {[Eu₂(DBTA)₃(DMF)₂]·DMF}_n (1) and {[Tb₂(DBTA)₃(DMF)₂]·DMF}_n (2) (H₂DBTA = 2,5-dibromoterephthalic acid), have been successfully synthesized by the solvothermal method. Single-crystal X-ray diffraction results proved that the complexes possess the same topological structure of a (4²·6)₂(4²·8⁴)(4⁷·6³)₂-connected net. The recognition of CN⁻ from interfering anions with a low detection limit by “turn-off” luminescence makes them promising candidates for the highly selective and sensitive detection of the cyanide ion. The Ln-MOFs 1 and 2 exhibit excellent chemical sensing properties for CN⁻ with efficiency, selectivity, and excellent performance in various mixed anions. The evaluation parameters, including the quenching constant and detection limit, have been investigated to obtain the detection performance for CN⁻.