Issue 31, 2022

Heterolytic carbon–iodine bond cleavage by a palladium(i) metalloradical

Abstract

The well-defined Pd(I) metalloradical [Pd(PtBu3)2]+ reacts with aryl and alkyl iodides at room temperature, yielding [Pd(PtBu3)(μ-I)]2 and phosphonium salts. Pd(II) aryl/alkyl derivates, reflecting net radical oxidative addition of the substrate to the metalloradical, are generated during the reaction and two examples have been isolated and crystallographically characterised.

Graphical abstract: Heterolytic carbon–iodine bond cleavage by a palladium(i) metalloradical

Supplementary files

Article information

Article type
Communication
Submitted
05 Jul 2022
Accepted
10 Jul 2022
First published
11 Jul 2022
This article is Open Access
Creative Commons BY license

Dalton Trans., 2022,51, 11617-11619

Heterolytic carbon–iodine bond cleavage by a palladium(I) metalloradical

M. J. G. Sinclair and A. B. Chaplin, Dalton Trans., 2022, 51, 11617 DOI: 10.1039/D2DT02152H

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