High performance visible light response of a Z-type Bi2WO6/BiOBr/RGO heterojunction photocatalyst for the degradation of norfloxacin

Abstract

A Bi₂WO₆/BiOBr/RGO (BWO/BOB/RGO) composite photocatalyst with a Z-type heterojunction was prepared by a simple one-pot hydrothermal method, and the micro-morphology and physicochemical properties of the prepared samples were characterized. After reacting under visible light for 120 min, the degradation rate of 20 mg L⁻¹ norfloxacin (NOR) by BWO/BOB/RGO was 95.12%, and the kinetic constant of the reaction was 6.42 times higher than that of pure BiOBr. Furthermore, BWO/BOB/RGO also shows good recycling stability and universality. The characterization results show that the improvement of the photocatalytic performance of the catalyst is mainly due to the heterojunction formed between Bi₂WO₆, RGO and BiOBr, which enhances the visible light absorption ability, accelerates the photogenerated electron migration and improves the electron–hole pair separation efficiency. The introduction of Bi₂WO₆ and RGO into the catalyst also increased its specific surface area and made it have more surface-active sites. The results of radical capture experiments showed that ˙O₂⁻ and h⁺ played an important role in the BWO/BOB/RGO reaction system, and the intermediate products and possible degradation pathways of the system were detected and analyzed. Furthermore, the electron transfer mechanism of the Z-type heterojunction using RGO as an electron transport medium and the mechanism of photocatalytic degradation of norfloxacin were proposed.