Issue 15, 2022
From the journal:

Materials Advances

Iodine-induced electrical conductivity of novel columnar lanthanide metal–organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand†

Monica A. Gordillo,a   Paola A. Benavides,a   Colin McMillen ORCID logo a  and  Sourav Saha ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Clemson University, 211 S. Palmetto Blvd., Clemson, SC, USA
E-mail: souravs@clemson.edu

Abstract

Novel columnar lanthanide metal–organic frameworks (Ln-MOFs) based on a butterfly-shaped electron-rich π-extended tetrathia-fulvalene ligand (ExTTFTB) were synthesized and their electronic properties were investigated. Upon iodine-induced ligand oxidation, the Tb-MOF displayed ca. 100-fold higher electrical conductivity (5 × 10−7 S m−1) than the neutral pristine MOF.

Graphical abstract: Iodine-induced electrical conductivity of novel columnar lanthanide metal–organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D2MA00606E
Article type
Communication
Submitted
29 May 2022
Accepted
04 Jul 2022
First published
07 Jul 2022
This article is Open Access
Creative Commons BY-NC license

Mater. Adv., 2022,3, 6157-6160

Permissions

Request permissions

Iodine-induced electrical conductivity of novel columnar lanthanide metal–organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

M. A. Gordillo, P. A. Benavides, C. McMillen and S. Saha, Mater. Adv., 2022, 3, 6157 DOI: 10.1039/D2MA00606E

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements