Synthesis of Pd nanorod arrays on Au nanoframes for excellent ethanol electrooxidation

Abstract

Au–Pd hollow nanostructures have attracted a lot of attention because of their excellent ethanol electrooxidation performance. Herein, we report a facile preparation of Au nanoframe@Pd array electrocatalysts in the presence of cetylpyridinium chloride. The reduced Pd atoms were directed to mainly deposit on the surface of the Au nanoframes in the form of rods, leading to the formation of Au nanoframe@Pd arrays with a super-large specific surface area. The red shift and damping of the plasmon peak were ascribed to the deposition of the Pd arrays on the surface of the Au nanoframes and nanobipyramids, which was verified by electrodynamic simulations. Surfactants, temperature and reaction time determine the growth process and thereby the architecture of the obtained Au–Pd hollow nanostructures. Compared with the Au nanoframe@Pd nanostructures and Au nanobipyramid@Pd arrays, the Au nanoframe@Pd arrays exhibit an enhanced electrocatalytic performance towards ethanol electrooxidation due to an abundance of catalytic active sites. The Au NF@Pd arrays display 4.1 times higher specific activity and 13.7 times higher mass activity than the commercial Pd/C electrocatalyst. Moreover, the nanostructure shows improved stability towards the ethanol oxidation reaction. This study enriches the manufacturing technology to increase the active sites of noble metal nanocatalysts and promotes the development of direct ethanol fuel cells.