Structural evolution of MXenes and their composites for electromagnetic interference shielding applications

Abstract

Nowadays, the extensive utilization of electronic devices and equipment inevitably leads to severe electromagnetic interference (EMI) issues. Therefore, EMI shielding materials have drawn considerable attention, and great effort has been devoted to the exploration of high-efficiency EMI shielding materials. As a novel kind of 2D transition metal carbide material, MXenes have been widely investigated for EMI shielding in the past few years due to their extraordinary electrical conductivity, large specific surface area, light weight, and easy processability. In view of the great achievements in MXene-based materials for EMI shielding, herein, we reviewed the recent studies on the structural design and evolution of MXenes and their composites for EMI shielding. First, the methods for structural control of MXenes, including HF etching, in situ HF etching, fluorine-free etching, electrochemical etching, and molten salt etching, are systematically summarized. Then we illustrate the fundamental relationship between the microstructure of MXenes and the EMI shielding mechanism. In the following, the effects of different synthesis methods and structures of MXene-based composite materials as well as their EMI shielding performances are comprehensively discussed. Lastly, future prospects for the development of MXene-based composite materials in EMI shielding applications are commented on.