Issue 1, 2022

Controlled assembly and reversible transformation of tuneable luminescent Mo8-R6G hybrids

Abstract

Fluorescent dyes such as rhodamine R6G usually suffer from quenching caused by aggregation in the solid state. Herein, we enhance the solid state luminescence of R6G by controlling assemblies of rhodamine R6G and [Mo8O26]4− based on the synergies between the anchoring and diluting effects. In addition, the hybrids represent reversible transformation and tunable luminescence by different loadings of the rhodamine 6G dye within the [Mo8O26]4− architecture. This work provides new ideas for the structural design, synthesis and transformation of POM-based hybrid materials, opening the way towards the design of novel multifunctional hybrid systems.

Graphical abstract: Controlled assembly and reversible transformation of tuneable luminescent Mo8-R6G hybrids

Supplementary files

Article information

Article type
Research Article
Submitted
10 Aug 2021
Accepted
29 Oct 2021
First published
29 Oct 2021

Inorg. Chem. Front., 2022,9, 78-82

Controlled assembly and reversible transformation of tuneable luminescent Mo8-R6G hybrids

H. Zeng, W. Wu, C. Wang, Z. Jiang and C. Zhan, Inorg. Chem. Front., 2022, 9, 78 DOI: 10.1039/D1QI01014J

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