Issue 7, 2022

Ferroelastic phase transition with large spontaneous strain caused by freezing the conformational dynamics of ammonium

Abstract

By adjusting the substituent group of the organic ammonium in three molecular ionic complexes, [A][Fe3O(O2CH)8(H2O)]2 (A = NH3(CH2)3NH3 for 1, CH3NH2(CH2)3NH3 for 2 and CH3CH2NH2(CH2)3NH2CH2CH3 for 3), crystallized in the 2/m point group at room temperature with similar structure, conformational transformation-caused dynamic disorder and pseudosymmetry is realized in 3. When the conformational interchange of the ammonium is frozen, the disorder–order 2/mF[1 with combining macron] ferroelastic phase transition is presented, which leads to dielectric relaxation and a large spontaneous strain of 0.207.

Graphical abstract: Ferroelastic phase transition with large spontaneous strain caused by freezing the conformational dynamics of ammonium

Supplementary files

Article information

Article type
Research Article
Submitted
14 Jan 2022
Accepted
06 Feb 2022
First published
08 Feb 2022

Inorg. Chem. Front., 2022,9, 1380-1385

Ferroelastic phase transition with large spontaneous strain caused by freezing the conformational dynamics of ammonium

L. Li, C. Ji, Y. Sun, Y. Jin, G. Ni, J. Sun, R. Han, J. Zhao and F. Liu, Inorg. Chem. Front., 2022, 9, 1380 DOI: 10.1039/D2QI00114D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements