Issue 2, 2022

Iridium(iii)-catalyzed two-fold C–H alkylation of BINOLs with allyl alcohols

Abstract

Ir(III)-Catalyzed C–H alkylation of BINOL units has been well examined by using allyl alcohols as coupling partners. Under the advantage of the pyridine guiding group, the efficient protocol allows the rapid synthesis of diverse BINOL carbonyl compounds with the retention of optical purity.

Graphical abstract: Iridium(iii)-catalyzed two-fold C–H alkylation of BINOLs with allyl alcohols

Supplementary files

Article information

Article type
Research Article
Submitted
04 Oct 2021
Accepted
04 Dec 2021
First published
07 Dec 2021

Org. Chem. Front., 2022,9, 471-475

Iridium(III)-catalyzed two-fold C–H alkylation of BINOLs with allyl alcohols

H. Liu, W. Chi, M. Lin and L. Dong, Org. Chem. Front., 2022, 9, 471 DOI: 10.1039/D1QO01486B

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