Preparation and application of polyethyleneimine-modified corncob magnetic gel for removal of Pb(ii) and Cu(ii) ions from aqueous solution

Abstract

As a biomass resource, corncob is a kind of agricultural by-product with wide sources and low cost. Because its composition contains a large number of functional polymers such as cellulose, chitosan, and semi chitosan, corncob can be chemically modified to prepare a variety of adsorption materials. In this study, a magnetic gel material (PEI-CC@Fe₃O₄) consisting of corncob modified by glutaraldehyde-crosslinked polyethyleneimine (PEI) was successfully prepared and applied to the adsorption of heavy metal ions in aqueous solutions. The structure, thermal stability, and adsorption of heavy metal ions of the magnetic gel material (PEI-CC@Fe₃O₄) were characterized by Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction phase analysis (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and X-ray photoelectron spectroscopy (XPS). The results showed that PEI was crosslinked to the corncob through Aldol reaction and Schiff-base reaction. The heavy metal ion adsorption experiment showed that the PEI-CC@Fe₃O₄ had better adsorption toward divalent copper ions and divalent lead ions at 303 K, and the maximum adsorption capacities reached 459.4 mg g⁻¹ and 290.8 mg g⁻¹, respectively. Moreover, the study of isothermal adsorption and adsorption kinetics shows that the adsorption process is pseudo-second-order kinetics model adsorption, which belongs to Langmuir isothermal adsorption. Such excellent adsorption performance will contribute to the application of corncob biomass materials in industrial polluted wastewater.