Catalytic graphitization assisted synthesis of Fe3C/Fe/graphitic carbon with advanced pseudocapacitance

Abstract

We report an environmentally friendly strategy for the synthesis of Fe₃C/Fe/graphitic carbon based on hydrothermal carbonization and graphitization of carbon spheres with potassium ferrate (K₂FeO₄) at 800 °C. The obtained sample consisting of Fe₃C/Fe nanoparticles and graphitic carbon (FC-1-8) delivered an enhanced pseudocapacitance of 428.0 F g⁻¹ at a current density of 1 A g⁻¹. After removal of the Fe₃C/Fe electroactive materials, the graphitic carbon (FC-1-8-HCl) possessed a large specific surface area (SSA) up to 2813.6 m² g⁻¹ with a capacity of 243.3 F g⁻¹ at 1 A g⁻¹, far outweighing the other amorphous carbon electrodes of FC-0-8 (carbon spheres annealed at 800 °C without the treatment of K₂FeO₄). The graphitic material with a porous structure could offer more electroactive sites and improved conductivity of the sample. This method provided guidelines for the synthesis of superior performance supercapacitors with synchronous graphitic carbon and electroactive species.