Efficient and ecofriendly cellulose-supported MIL-100(Fe) for wastewater treatment

Abstract

Due to their efficiency and accessibility, benzodiazepines are widely manufactured and consumed and as a result, they can be found in almost all wastewaters. Among the materials that were used for the removal of drug contaminants from wastewater, metal–organic frameworks (MOFs) demonstrated unique properties. In this regard, a composite of carboxymethylated cellulose (CMC) and MIL-100(Fe) was prepared via a sonochemical method and used for the removal of lorazepam from wastewater in various conditions. A maximum capacity of 811 mg g⁻¹ was achieved which is considered a great improvement compared to bare MIL-100(Fe) (150 mg g⁻¹) and other previously reported adsorbents. It is noteworthy that the efficiency of the adsorbent did not reduce in the second and third cycle of adsorption/desorption. Moreover, the effect of pH, dose of adsorbent, isotherms and the kinetics of this process were studied using UV-vis and HPLC analyses and the adsorbents were fully characterized with PXRD, TGA, BET, SEM, ZP and FT-IR techniques. Our findings demonstrate that this composite is clearly a green, recyclable and efficient adsorbent for the removal of lorazepam and opens our way to further potential applications in the removal of other active pharmaceutical ingredients.