Remediation of PAHs contaminated industrial soils by hypochlorous acid: performance and mechanisms

Abstract

Polycyclic aromatic hydrocarbons (PAHs) mainly originate from incomplete combustion of organic substances and are carcinogenic, mutagenic and teratogenetic, posing a high risk to the ecosystem and human health. The remediation of soils contaminated with PAHs has aroused wide public concern. In this study, hypochlorous acid (HOCl) was applied to realize PAHs removal from industrial contaminated soil with an extremely high degradation efficiency of 93.33% when the initial chlorine concentration was 5000 mg L⁻¹. The degradation behavior of PAHs by HOCl oxidation was investigated in detail. Parameters including chlorine dosage, pH and temperature that had effects on the degradation process were evaluated systematically. The removal of PAHs was followed well with the pseudo-first-order kinetic model. It is found that HOCl and OH˙ were major contributors to the degradation products of chlorinated and oxygenated PAHs. This research provided an easy-operating and energy-saving way to realize the remediation of PAHs contaminated industrial soil practically with high efficiency.