Electrochemical paraquat sensor based on lead oxide nanoparticles

Abstract

1,1-Dimethyl-4,4-bipyridinium dichloride known as paraquat is a popular well-known herbicide that is widely used in agriculture around the world. However, paraquat is a highly toxic chemical causing damage to vital organs including the respiratory system, liver, heart, and kidneys and death. Therefore, detection of paraquat is still necessary to protect life and the environment. In this work, an electrochemical sensor based on lead oxide nanoparticles (PbO-NPs) modified on a screen-printed silver working electrode (SPE) has been fabricated for paraquat detection at room temperature. The PbO-NPs have been synthesized by using a sparking method via two Pb metal wires. The electrochemical paraquat sensors have been prepared by a simple drop-casting of PbO-NPs solution on the surface of the SPE. The PbO-NPs/SPE sensor exhibits a linear response in the range from 1 mM to 5 mM with good reproducibility and high sensitivity (204.85 μA mM⁻¹ cm⁻²) for paraquat detection at room temperature. The PbO-NPs/SPE sensor shows high selectivity to paraquat over other popular herbicides such as glyphosate, glufosinate-ammonium and butachlor-propanil. The application of the PbO-NPs/SPE sensor is also demonstrated via the monitoring of paraquat contamination in juice and milk.