Magnetic properties, magnetocaloric effect, and critical behaviors in Co1−xCrxFe2O4

Abstract

This research work focuses on the magnetic properties, nature of the magnetic phase transition, magnetocaloric effect, and critical scaling of magnetization of various Co_1−xCr_xFe₂O₄ (x = 0, 0.125, 0.25, 0.375, and 0.5). The tunability of the magnetic moment, exchange interactions, magnetocrystalline anisotropy constant, and microwave frequency using Cr³⁺ content has been found. The nature of the magnetic phase transitions for all the Cr³⁺ concentrations exhibits as second order which has been confirmed from the analysis of critical scaling, universal curve scaling, and scaling analysis of the magnetocaloric effect. The critical exponent analysis for all samples was performed from the modified Arrott-, and Kouvel–Fisher-plots. These critical analyses suggest that x = 0.125, 0.250, and 0.375 samples show reliable results in the magnetocaloric effect with relative cooling power (RCP) values in the range of 128–145 J kg⁻¹. On the other hand, x = 0.00, and 0.500 samples exhibit inconsistent RCP values. The universal curve scaling also confirms the reliability of the magnetocaloric effect of the investigated samples.