Issue 29, 2022, Issue in Progress

Direct phosphorylation of benzylic C–H bonds under transition metal-free conditions forming sp3C–P bonds

Abstract

Direct phosphorylation of benzylic C–H bonds was achieved in a biphasic system under transition metal-free conditions. A selective radical/radical sp3C–H/P(O)–H cross coupling was proposed, and various substituted toluenes were applicable. The transformation provided a promising method for constructing sp3C–P bonds.

Graphical abstract: Direct phosphorylation of benzylic C–H bonds under transition metal-free conditions forming sp3C–P bonds

Supplementary files

Article information

Article type
Paper
Submitted
03 May 2022
Accepted
16 Jun 2022
First published
24 Jun 2022
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2022,12, 18441-18444

Direct phosphorylation of benzylic C–H bonds under transition metal-free conditions forming sp3C–P bonds

Q. Li, C. Zhao, T. Chen and L. Han, RSC Adv., 2022, 12, 18441 DOI: 10.1039/D2RA02812C

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements