Preparation, characterization, and performance of PES/GO woven mixed matrix nanocomposite forward osmosis membrane for water desalination

Abstract

Mixed matrix woven forward osmosis (MMWFO) membranes made of polyethersulfone (PES)/graphene oxide nanosheets (GO NSs) were made by inserting varying wt% ratios of GO NSs (zero to 0.1 wt%) into the PES matrix. A coated woven fabric material was used to cast the membrane polymer solution. The physical characteristics and chemical structures of the produced PES/GO MMWFO membranes were studied, including contact angle, hydrophilicity, porosity, tortuosity, function groups, chemical and crystallographic structures, nanomorphologies, and surface roughness. The performance of the prepared PES/GO FO membranes for water desalination was evaluated in terms of pure water flux (J_w), reverse salt flux (J_s), and salt rejection (SR). The hydrophilicity and porosity of the FO membrane improved with the addition of GO NSs, as did water permeability due to the development of multiple skin-layer structures with greater GO NS loading. These GO NSs establish shortcut pathways for water molecules to move through, reducing support layer tortuosity by three times, lowering support layer structural features, and minimizing internal concentration polarization (ICP). The PES/0.01 wt% GO MMWFO membrane with a total casting thickness of 215 μm and 1 M NaCl concentration had the best performance, with the highest J_w (114.7 LMH), lowest J_s (0.03 GMH), and lowest specific reverse solute flux (J_s/J_w = 0.00026 g L⁻¹), as well as a more favorable structural parameter (S = 149 μm). The performance of our optimized membrane is significantly better than that of the control woven commercial cellulose triacetate (CTA) FO membrane under optimal FO conditions. As the NaCl concentration increased from 0.6 to 2 M, J_w increased from 105 to 127 LMH which is much higher than the J_w of the commercial one (7.2 to 15 LMH). Our FO membranes have an SR of 99.2%@0.65 M NaCl, which is significantly greater than that of the CTA membrane.