Graphene oxide membrane chemically modified by electron-transfer diazonium chemistry for efficient dye separation

Abstract

By chemical modification of the graphene oxide (GO) surface via diazonium chemistry, we introduce nitrobenzene groups as new interlayer pillars to GO memebranes like the surface oxygen-containing functional groups. The larger pillar can finely enlarge the interlayer space of the GO membrane. The filtration performance of modified GO membranes with different mass ratios of nitrobenzene diazonium tetrafluoroborate (NDT) were tested for EB, DR81, and MB. Notably, when the GO : NDT ratio is 1 : 1, it is found that the water flux can be enhanced by more than twice and by nearly 1.4 times its value for EB and DR81, respectively, while maintaining a high rejection (92% for EB and 95% for DR81). In conclusion, the chemical modification of GO through the dediazonization reaction of NDT can indeed improve the separation efficiency of the dye.