Selective detection of methanol vapour from a multicomponent gas mixture using a CNPs/ZnO@ZIF-8 based room temperature solid-state sensor

Abstract

Methanol vapour is harmful to human health if it is inhaled, swallowed, or absorbed through the skin. Solid-state gas sensors are a promising system for the detection of volatile organic compounds, unfortunately, they can have poor gas selectivity, low sensitivity, an inferior limit of detection (LOD), sensitivity towards humidity, and a need to operate at higher temperatures. A novel solid-state gas sensor was assembled using carbon nanoparticles (CNPs), prepared from a simple pyrolysis reaction, and zinc oxide@zeolitic imidazolate framework-8 nanorods (ZnO@ZIF-8 nanorods), synthesised using a hydrothermal method. The nanomaterials were characterized using scanning electron microscopy, transmission electron microscopy, powder X-ray diffraction, X-ray photoelectron spectroscopy Raman spectroscopy, and Fourier transform infrared spectroscopy. The ZnO@ZIF-8 nanorods were inactive as a sensor, the CNPs showed some sensor activity, and the CNPs/ZnO@ZIF-8 nanorod composite performed as a viable solid-state sensor. The mass ratio of ZnO@ZIF-8 nanorods within the CNPs/ZnO@ZIF-8 nanorod composite was varied to investigate selectivity and sensitivity for the detection of ethanol, 2-propanol, acetone, ethyl acetate, chloroform, and methanol vapours. The assembled sensor composed of the CNPs/ZnO@ZIF-8 nanorod composite with a mass ratio of 1.5 : 6 showed improved gas sensing properties in the detection of methanol vapour with a LOD of 60 ppb. The sensor is insensitive to humidity and the methanol vapour sensitivity was found to be 0.51 Ω ppm⁻¹ when detected at room temperature.