Electrospun 1D-NiO hollow nanowires on glass support for the sunlight-driven photodegradation of methylene blue

Abstract

Sunlight-driven semiconductor photocatalysts have received substantial attention due to environmental degradation, but a simple and reusable photocatalyst design has been a challenging task. Herein, we report the fabrication of a one-dimensional hollow semiconducting nanowire structure by electrospun-mediated nickel oxide nanowires (NiO NWs) as a reusable photocatalyst by direct deposition on glass substrates. The effective control of the sunlight-driven hollow nanowires as the photocatalyst has a high surface area for multiple light-harvesting and interface redox reactions, a nanostructured thin shell for accelerated charge separation, transportation, and a large length-diameter ratio for easy recycling. The electrospun NiO NWs were nest-like hollow nanostructure fibers, crystalline, and with a high density, and the synthesis and parameters were thoroughly investigated to achieve the characteristic shape of the hollow NiO NWs. Further, the photocatalytic activity of the NiO NWs on glass substrates for the selective breakdown of methylene blue (MB) under sunlight irradiation to optimize the efficiency of the NiO NWs, such as degradation techniques, concentration, and pH of the MB solution. The stability and reusability of the NiO NWs were tested successfully in several reusable cycles, with only a 2% degradation difference. The reaction rate was found to be 0.054 min⁻¹ for MB (5 μM) and 0.033 min⁻¹ for MB (10 μM) at pH 11 for 60 min, and the higher activity parameter was calculated to be 3.3 × 10⁻³ min⁻¹ mg⁻¹ L⁻¹ due to their hollow structure and effective area of the NiO NWs. They contain more superficially-entrapped holes that change with chemisorbed oxyhydroxyl OH or H₂O to form OH⁻ radicals. The specific active hollow surface area rises, whereas the rate of optical-electronic hole recombination drops. The photocatalytic degradation performance of the fabricated one-step electrospun hollow NiO NW-based photocatalyst on substrates showed speed, reusability, and promoted the formation of radicals capable of decomposing organic pollutants, which were shown to have application in photocatalysis.