pH and light dual stimuli-responses of mixed system of 2-hydroxyl-propanediyl-α,ω-bis(dimethyldodecyl ammonium bromide) and trans-ortho-hydroxyl cinnamic acid

Abstract

Stimuli-responsive smart supramolecular self-assembly with controllable morphology and adjustable rheological property has attracted widespread concern of scientists in recent years due to the great potential application in microfluidics, controlled release, biosensors and so on. In this study, a pH and UV light dual stimuli-responsive system was constructed by combining Gemini surfactant 2-hydroxyl-propanediyl-α,ω-bis(dimethyldodecyl ammonium bromide) (12-3(OH)-12·2Br⁻) with trans-ortho-hydroxyl cinnamic acid (trans-OHCA) in aqueous solution. The phase behavior and stimuli-responsive behavior of the system including the microstructural transition, rheological property, intermolecular interaction, and isomerization reaction were explored by various experiment techniques such as rheometer, UV-vis spectrum, polarized optical microscopy (POM), transmission electron microscopy (TEM), dynamic light scattering (DLS) as well as theoretical calculation. The system displays abundant phase behaviors that supramolecular self-assemblies of different morphologies in different states such as spherical micelle, wormlike micelle, lamellar liquid crystal, and aqueous two phase system (ATPS) were observed even at lower concentration, which provide the research basis on the abundant stimuli-responsiveness of the system. The results prove that the multiple ionization and the photo-isomerization of trans-OHCA endow the system with plentiful responses to pH and UV light stimuli. It is expected that this study on the dual stimuli-responsive system with abundant self-assembly behaviors and adjustable rheological behaviors would be of theoretical and practical importance, which would provide essential guidance in designing and constructing smart materials with multiple stimuli-responses.