A double co-sensitization strategy using heteroleptic transition metal ferrocenyl dithiocarbamate phenanthrolene-dione for enhancing the performance of N719-based DSSCs

Abstract

Three new heteroleptic dithiocarbamate complexes with formula [M(Phen-dione)(Fcdtc)]PF₆ (where M = Ni(II) Ni-Fc, Cu(II) Cu-Fc) and [Co(Phen-dione)(Fcdtc)₂]PF₆ (Co-Fc) (Fcdtc = N-ethanol-N-methylferrocene dithiocarbamate and Phen-dione = 1,10-phenanthroline-5,6-dione; PF₆⁻ = hexafluorophosphate) were synthesized and characterized using microanalysis, FTIR, electronic absorption spectroscopy and mass spectrometry. The solution state electronic absorption spectroscopy for all three complexes displayed a band at ∼430 nm corresponding to the ferrocene unit and another low-intensity band in the visible region arising because of the d–d transitions. These newly synthesized complexes were used as co-sensitizers for the state-of-the-art di-tetrabutylammonium cis-bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II) (N719) dye in dye-sensitized solar cells (DSSCs). Among the three co-sensitizers/co-adsorbent-based DSSC set-ups, the assembly fabricated using Co-Fc/N719 displayed good photovoltaic performance with 5.31% efficiency (η) while a new triple component strategy inculcating N719, Co-Fc and Cu-Fc dyes offered the best photovoltaic performance with 6.05% efficiency (η) with incident photon to current conversion efficiency (IPCE) of 63%. This indicated an upliftment of the DSSC performance by ∼38% in comparison to the set-up constructed by employing only N719 dye (η = 4.39%) under similar experimental conditions.