UV-curable self-matting waterborne polyurethane acrylate coating via self-wrinkled surface during curing in open-air

Abstract

This study developed and evaluated a series of ultraviolet (UV) curable self-matting waterborne polyurethane acrylate (UV-WPUA) coatings based on the self-wrinkled surface during UV-curing in the open-air. This method is simple, efficient, eco-friendly, and it does not require complicated or expensive equipment. The FT-IR spectrum indicates that the peaks of CC in UV-WPUA have disappeared after UV irradiation. The gloss value of the UV-WPUA cured film can be affected by the wrinkles on the surface of the film and adjusted it by controlling the content of the photoinitiator in the liquid coating, since the content influences the dimensions of the wrinkles. As the height of the wrinkle increased, the gloss value of the UV-WPUA cured film decreased, and when the incident angles are 20° and 60°, the gloss values are less than 3 GU and 5 GU, respectively. Moreover, the cured film has a maximum water contact angle of 109°, which is affected by wrinkles and positively correlated with the surface roughness of the film. Furthermore, the cured film has excellent properties of thermal stability, tensile strength, pencil hardness, cross-cut adhesion and resistance to abrasion properties, making it well suited for the furniture, leather, and textile applications.