Colloidal membranes of chiral rod-like particles

Abstract

We study colloidal (or smectic) membranes composed of chiral rod-like particles through Monte Carlo simulations. These objects are formed due to the presence of Asakura-Oosawa spheres acting as depletants and creating an effective attraction between the rods. The membranes' shape and structure can be influenced by several parameters, e.g. the number of spheres and rods, their length and their interaction. In order to compare simulation results to an elastic theory, we follow two ansatzes, approximating the free elastic energy in different ways. Both of them lead to reasonable results and capture the behaviour of the colloidal membrane system. One approximation, however, is not suited for achiral rods, where twisting occurs due to surface energy rather than elastic energy. We extract the inverse cholesteric pitch and twist penetration depth for chiral rods with this approximation. The other one is used to introduce a complementary method to estimate elastic constants from the shape of colloidal membranes. Besides, we describe the transition from homogeneously twisted membranes to membranes composed of substructures that occur when the chiral interaction exceeds a length-dependent threshold. We believe that our detailed study and discussion of different aspects of this model system are valuable from a fundamental research viewpoint and suitable for material design suggestions.