Ultrahigh energy harvesting properties in temperature-insensitive eco-friendly high-performance KNN-based textured ceramics†
Abstract
Mechanical energy-driven wireless charging technology has recently gained increasing attention. In this work, high-performance potassium sodium niobate (KNN)-based textured ceramics and their potential application in energy harvesting devices are systematically investigated. A series of lead-free 0.99K0.5Na0.5Nb(1−x)TaxO3–0.01Bi(Ni2/3Nb1/3)O3 [KNNTa–BNN] piezoceramics were designed and prepared to search for good comprehensive properties. The comprehensive performance of KNN-based piezoelectric ceramics has reached a new level in T–Ta-9 (d33 ∼ 435 pC N−1, kp ∼ 71%, Tc ∼ 360 °C) via the synergy of the textured structure (f(00l) > 94%) and multiphase coexistence (O–T) near room temperature. Based on the advanced in situ TEM and PFM analyses, it was found that the regular large-scale domains and corresponding poling patterns of the T–Ta-9 can be well maintained at relatively high temperatures (180–330 °C), resulting in excellent temperature stability. Hence, the d33 value of T–Ta-9 can be maintained above 300 pC N−1 over a wide range from room temperature to 300 °C, which rarely happens in the previously reported KNN-based materials. More importantly, the piezoelectric circular diaphragm (PCD) vibration energy harvester based on the T–Ta-9 texture ceramic possesses high output voltage (U ∼ 13 V) and output power (W ∼ 3 mW), and can still maintain above 60% after being heated at 200 °C for 30 min. This work represents a significant advancement in the lead-free piezoelectric energy-harvesting field (especially for high-temperature applications) and can provide guidelines for future efforts in this direction.