Issue 38, 2023

Comment on “Carbon content drives high temperature superconductivity in a carbonaceous sulfur hydride below 100 GPa” by G. A. Smith, I. E. Collings, E. Snider, D. Smith, S. Petitgirard, J. S. Smith, M. White, E. Jones, P. Ellison, K. V. Lawler, R. P. Dias and A. Salamat, Chem. Commun., 2022, 58, 9064

Abstract

Experimental data supporting the claim that a carbonaceous sulfur hydride (CSH) under pressure is a high temperature superconductor were presented. Here we report results of a mathematical analysis that indicates that with probability larger than 1–10−338 some of those data were not measured in a laboratory, contrary to what the papers claim. This finding undermines confidence in the claim that any of the experimental evidence reported in those papers reflects the properties of real physical samples of CSH.

Graphical abstract: Comment on “Carbon content drives high temperature superconductivity in a carbonaceous sulfur hydride below 100 GPa” by G. A. Smith, I. E. Collings, E. Snider, D. Smith, S. Petitgirard, J. S. Smith, M. White, E. Jones, P. Ellison, K. V. Lawler, R. P. Dias and A. Salamat, Chem. Commun., 2022, 58, 9064

Associated articles

Article information

Article type
Comment
Submitted
26 Sep 2022
Accepted
13 Apr 2023
First published
21 Apr 2023

Chem. Commun., 2023,59, 5765-5770

Comment on “Carbon content drives high temperature superconductivity in a carbonaceous sulfur hydride below 100 GPa” by G. A. Smith, I. E. Collings, E. Snider, D. Smith, S. Petitgirard, J. S. Smith, M. White, E. Jones, P. Ellison, K. V. Lawler, R. P. Dias and A. Salamat, Chem. Commun., 2022, 58, 9064

J. E. Hirsch, Chem. Commun., 2023, 59, 5765 DOI: 10.1039/D2CC05277F

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