Issue 12, 2023

Extending the Hammett correlation to mechanochemical reactions

Abstract

Using Raman in situ monitoring and mechanochemistry-specific kinetic analysis, we find a correlation between the reaction probability and the Hammett constants in a model mechanochemical reaction of imine formation, indicating that the body of knowledge developed in physical–organic chemistry could be transferable to ball milling reactions in the solid state.

Graphical abstract: Extending the Hammett correlation to mechanochemical reactions

Supplementary files

Article information

Article type
Communication
Submitted
29 Nov 2022
Accepted
13 Jan 2023
First published
20 Jan 2023
This article is Open Access
Creative Commons BY license

Chem. Commun., 2023,59, 1629-1632

Extending the Hammett correlation to mechanochemical reactions

L. Vugrin, M. Carta, F. Delogu and I. Halasz, Chem. Commun., 2023, 59, 1629 DOI: 10.1039/D2CC06487A

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