Issue 30, 2023
From the journal:

Chemical Communications

Partial quaternization promoted metal–organic frameworks for efficient photocatalytic removal of chromium(vi)†

Xiaocong Tang,ab   Xu Wu,a   Hao Wu,c   Xinyu Zhang,a   Mingbao Feng,ab   Tong Ouyang,ab   Huanting Wang ORCID logo d  and  Ranwen Ou ORCID logo *ab  

* Corresponding authors

a College of the Environment & Ecology, Xiamen University, Xiamen 361104, P. R. China
E-mail: ouranwen@xmu.edu.cn

b Key Laboratory of the Coastal and Wetland Ecosystem (Xiamen University), Ministry of Education, P. R. China

c Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China

d Department of Chemical Engineering, Monash University, Clayton, Victoria 3800, Australia

Abstract

A one-step strategy is applied to partially quaternize the ligand of UiO-66-NH2, and the resultant UiO-66-N(CH3)3+ showed greatly improved photocatalytic performance for Cr(VI) reduction, with the apparent reaction rate constant k increasing by 8.3 times. This strategy could be used to effectively promote the performance of other MOFs-NH2, demonstrating general applicability.

Graphical abstract: Partial quaternization promoted metal–organic frameworks for efficient photocatalytic removal of chromium(vi)

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Article information

DOI
https://doi.org/10.1039/D2CC06563K
Article type
Communication
Submitted
02 Dec 2022
Accepted
20 Mar 2023
First published
20 Mar 2023

Chem. Commun., 2023,59, 4507-4510

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Partial quaternization promoted metal–organic frameworks for efficient photocatalytic removal of chromium(VI)

X. Tang, X. Wu, H. Wu, X. Zhang, M. Feng, T. Ouyang, H. Wang and R. Ou, Chem. Commun., 2023, 59, 4507 DOI: 10.1039/D2CC06563K

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