Recent advances of slippery liquid-infused porous surfaces with anti-corrosion

Abstract

Metal materials are susceptible to the influence of environmental media, and chemical or electrochemical multiphase reactions occur on the metal surface, resulting in the corrosion of metal materials, which can directly damage the geometry and reduce the physical properties of metal materials. This corrosion damage can seriously affect the long-term use of metal materials in marine equipment and the aerospace industry, and other fields. Inspired by the special microstructure and slippery properties of natural nepenthes intine, researchers have prepared slippery liquid-infused porous surfaces (SLIPS) with a stable continuous lubricant layer by injecting low-surface-energy lubricants into a substrate with a micro/nano-porous structure. This surface has excellent hydrophobicity, low friction, non-adhesiveness, and self-healing properties. The broad application prospects of SLIPS in the fields of anti-corrosion, anti-icing, anti-bacteria, and anti-fouling have made it a hot research topic directing the study of biomimetic materials at present. However, SLIPS are susceptible to environmental shear forces, such as ocean flow or extraneous fluids, resulting in destruction of the porous structure and loss of surface lubricant, thereby depriving SLIPS of the ability to protect metals from corrosion. Therefore, it is important for metal corrosion protection to find ways to improve the stability and extend the service life of SLIPS. Over the last several years, research into and development of SLIPS have come a long way. Herein, a summary of available reports on SLIPS is given in terms of design principles and their performance characteristics, the construction of rough/porous substrate structures, the choice of low-surface-energy modifiers and lubricants, and lubricant infusion methods. Ways of constructing different substrate structures and the characteristics, advantages, and disadvantages of choosing various modifiers and lubricants to prepare the surface are compared. Finally, a comprehensive summary and outlook of SLIPS with anti-corrosion properties are provided. We are convinced that a comprehensive review of SLIPS will provide important guidance and strong reference for the design and preparation of green and economical SLIPS with anti-corrosion capabilities in the future.