Synthesis of a rhodium(iii) dinitrogen complex using a calix[4]arene-based diphosphine ligand†
Abstract
The synthesis and characterisation of the rhodium(III) dinitrogen complex [Rh(2,2′-biphenyl)(CxP2)(N2)]+ are described, where CxP2 is a trans-spanning calix[4]arene-based diphosphine and the dinitrogen ligand is projected into the cavity of the macrocycle.
![Graphical abstract: Synthesis of a rhodium(iii) dinitrogen complex using a calix[4]arene-based diphosphine ligand](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=D2CC06837K&imageInfo.ImageIdentifier.Year=2023)
- This article is part of the themed collection: 2023 Pioneering Investigators
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