Issue 15, 2023

A hexagon based Mn(ii) rod metal–organic framework – structure, SF6 gas sorption, magnetism and electrochemistry

Abstract

A manganese(II) metal–organic framework based on the hexatopic hexakis(4-carboxyphenyl)benzene, cpb6−: [Mn3(cpb)(dmf)3], was solvothermally prepared showing a Langmuir area of 438 m2 g−1, rapid uptake OF sulfur hexafluoride (SF6) as well as electrochemical and magnetic properties, while single crystal diffraction reveals an unusual rod-MOF topology.

Graphical abstract: A hexagon based Mn(ii) rod metal–organic framework – structure, SF6 gas sorption, magnetism and electrochemistry

Supplementary files

Article information

Article type
Communication
Submitted
19 Dec 2022
Accepted
25 Jan 2023
First published
25 Jan 2023
This article is Open Access
Creative Commons BY license

Chem. Commun., 2023,59, 2106-2109

A hexagon based Mn(II) rod metal–organic framework – structure, SF6 gas sorption, magnetism and electrochemistry

F. M. Amombo Noa, O. Cheung, M. Åhlén, E. Ahlberg, P. Nehla, G. Salazar-Alvarez, S. Ershadrad, B. Sanyal and L. Öhrström, Chem. Commun., 2023, 59, 2106 DOI: 10.1039/D2CC06916D

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