is the important electrochemical intermediate in Li–S batteries of highly solvating solvents. Herein, the dissociation of 
into 
is deeply studied. light is proven to promote the formation of 
from the dissociation of 
. Accordingly, a strategy of pre-introducing highly active 
into DMSO-based electrolyte is proposed to activate sulfur cathodes of Li–S batteries.
B. Zhang, Z. Wang, H. Ji, H. Zhang, L. Li, J. Hu, S. Li and J. Wu, Chem. Commun., 2023, 59, 4237 DOI: 10.1039/D3CC00120B
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