Issue 28, 2023
From the journal:

Chemical Communications

Facile preparation of optically active helical polycarbenes with salicylate substituents and their postpolymerization modification†

Hui Zou, ORCID logo *a   Shan Tai,a   Shu-Yang Zhao,a   Li Zhou, ORCID logo a   Na Liu*b  and  Zong-Quan Wu ORCID logo *c  

* Corresponding authors

a Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, Anhui Province 230009, China
E-mail: zouh@huft.edu.cn

b The School of Pharmaceutical Sciences, Jilin University, 1266 Fujin Road, Changchun, Jilin Province 130021, China
E-mail: liuna606@jlu.edu.cn

c State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China
E-mail: zqwu@jlu.edu.cn

Abstract

Optically active helical polycarbenes were constructed through the living and controlled helix-sense-selective polymerization (HSSP) of methyl salicylate modified diazoacetate monomer catalysed via π-allylPdCl with chiral phosphine ligands. The obtained helical polycarbenes could undergo postpolymerization modification to afford functional polycarbenes efficiently.

Graphical abstract: Facile preparation of optically active helical polycarbenes with salicylate substituents and their postpolymerization modification

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Article information

DOI
https://doi.org/10.1039/D3CC00237C
Article type
Communication
Submitted
16 Jan 2023
Accepted
13 Mar 2023
First published
13 Mar 2023

Chem. Commun., 2023,59, 4201-4204

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Facile preparation of optically active helical polycarbenes with salicylate substituents and their postpolymerization modification

H. Zou, S. Tai, S. Zhao, L. Zhou, N. Liu and Z. Wu, Chem. Commun., 2023, 59, 4201 DOI: 10.1039/D3CC00237C

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