Issue 28, 2023
From the journal:

Chemical Communications

Electrophilicity of neutral square-planar organosilver(iii) compounds†

Daniel Joven-Sancho, ORCID logo a   Luca Demonti,b   Antonio Martín, ORCID logo a   Nathalie Saffon-Merceron,c   Noel Nebra, ORCID logo *b   Miguel Baya ORCID logo a  and  Babil Menjón ORCID logo *a  

* Corresponding authors

a Instituto de Síntesis Química y Catálisis Homogénea (iSQCH), CSIC-Universidad de Zaragoza, Zaragoza 50009, Spain
E-mail: b.menjon@csic.es

b Laboratoire Hétérochimie Fondamentale et Appliquée (LHFA), Université Paul Sabatier, CNRS, 118 Route de Narbonne, Toulouse 31062, France
E-mail: noel.nebra-muniz@univ-tlse3.fr

c Institut de Chimie de Toulouse ICT-UAR2599, Université de Toulouse UPS, CNRS, 118 route de Narbonne, Toulouse 31062, France

Abstract

Neutral Ag(III) complexes stabilised with just monodentate ligands are here unambiguously established. In a series of square-planar (CF3)3Ag(L) compounds with hard and soft Group 15 donor ligands, L, the metal center has been found to exhibit substantial acidity favouring apical coordination of an additional ligand under no coordination constraints.

Graphical abstract: Electrophilicity of neutral square-planar organosilver(iii) compounds

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Article information

DOI
https://doi.org/10.1039/D3CC00493G
Article type
Communication
Submitted
02 Feb 2023
Accepted
22 Feb 2023
First published
24 Feb 2023
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2023,59, 4166-4168

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Electrophilicity of neutral square-planar organosilver(III) compounds

D. Joven-Sancho, L. Demonti, A. Martín, N. Saffon-Merceron, N. Nebra, M. Baya and B. Menjón, Chem. Commun., 2023, 59, 4166 DOI: 10.1039/D3CC00493G

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