Issue 31, 2023
From the journal:

Chemical Communications

Molybdenum(iv) β-diketonate complexes as highly active catalysts for allylic substitution reactions†

Fabio Masero ORCID logo a  and  Victor Mougel ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Applied Biosciences, Laboratory of Inorganic Chemistry, ETH Zurich, 8093 Zurich, Switzerland
E-mail: mougel@inorg.chem.ethz.ch

Abstract

The synthesis and characterization of a series of Mo(IV) bis-β-diketonate (Rdiket, R = Me, tBu, Ph) dichloride (RMoIVCl2) and bistriflate (RMoIV(OTf)2) complexes are reported. All complexes are characterized in solid and solution state by XRD and 1H NMR spectroscopy. We demonstrate that the bistriflate complexes constitute highly active catalysts for allylic substitution reactions.

Graphical abstract: Molybdenum(iv) β-diketonate complexes as highly active catalysts for allylic substitution reactions

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Article information

DOI
https://doi.org/10.1039/D3CC00572K
Article type
Communication
Submitted
15 Feb 2023
Accepted
14 Mar 2023
First published
14 Mar 2023
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2023,59, 4636-4639

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Molybdenum(IV) β-diketonate complexes as highly active catalysts for allylic substitution reactions

F. Masero and V. Mougel, Chem. Commun., 2023, 59, 4636 DOI: 10.1039/D3CC00572K

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