Ferrocene-driven single-chain polymer compaction

Sebastian Gillhuber; Joshua O. Holloway; Hendrik Frisch; Florian Feist; Florian Weigend; Christopher Barner-Kowollik; Peter W. Roesky

doi:10.1039/D3CC00736G

Ferrocene-driven single-chain polymer compaction†

Sebastian Gillhuber,

^abc Joshua O. Holloway,

^bc Hendrik Frisch,

^bc Florian Feist,

^d Florian Weigend,

^e Christopher Barner-Kowollik

*^bcd and Peter W. Roesky

*^a

Author affiliations

* Corresponding authors

^a Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, Karlsruhe 76131, Germany
E-mail: roesky@kit.edu

^b School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane QLD 4000, Australia
E-mail: christopher.barnerkowollik@qut.edu.au

^c Centre for Materials Science, Queensland University of Technology (QUT), 2 George Street, Brisbane QLD 4000, Australia

^d Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen 76344, Germany
E-mail: christopher.barner-kowollik@kit.edu

^e Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße 4, Marburg 35043, Germany

Abstract

We introduce single-chain nanoparticles (SCNPs) exclusively folded by covalently bonded ferrocene units. Specifially, we demonstrate the ability of 2-ferrocenyl-1,10-phenanthroline to fuse single-chain collapse with the concomitant introduction of a donor functionality allowing the installation of a Pd-catalytic site, affording the first heterobimetallic ferrocene-functionalized SCNP.

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Article information

DOI: https://doi.org/10.1039/D3CC00736G
Article type: Communication
Submitted: 16 Feb 2023
Accepted: 22 Mar 2023
First published: 30 Mar 2023
This article is Open Access

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Chem. Commun., 2023,59, 4672-4675

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Ferrocene-driven single-chain polymer compaction

S. Gillhuber, J. O. Holloway, H. Frisch, F. Feist, F. Weigend, C. Barner-Kowollik and P. W. Roesky, Chem. Commun., 2023, 59, 4672 DOI: 10.1039/D3CC00736G

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Chemical Communications

Ferrocene-driven single-chain polymer compaction†

Abstract

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Ferrocene-driven single-chain polymer compaction

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