Issue 48, 2023
From the journal:

Chemical Communications

Complexation with pagoda[n]arene (n = 4, 5) protects ferrocenium from oxidation†

Gui-Hua Chen,a   Yi-Meng Duan,a   Ying Li,a   Xiao-Ni Han,b   Kun-Peng Wang, ORCID logo *a   Zhi-Qiang Hu*a  and  Chuan-Feng Chen ORCID logo *bc  

* Corresponding authors

a Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, China
E-mail: wangkunpeng@qust.edu.cn, huzhiqiang@qust.edu.cn

b Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: cchen@iccas.ac.cn

c University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

The complexation behaviors of pagoda[n]arenes (n = 4, 5) with ferrocene, ferrocenium and analogues cobaltocenium were studied. The inclusion complexes of pagoda[n]arenes can protect ferrocenium from oxidation in organic solvents and improve the stability and oxygen resistance of ferrocenium.

Graphical abstract: Complexation with pagoda[n]arene (n = 4, 5) protects ferrocenium from oxidation

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Article information

DOI
https://doi.org/10.1039/D3CC01202F
Article type
Communication
Submitted
10 Mar 2023
Accepted
22 May 2023
First published
23 May 2023

Chem. Commun., 2023,59, 7431-7434

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Complexation with pagoda[n]arene (n = 4, 5) protects ferrocenium from oxidation

G. Chen, Y. Duan, Y. Li, X. Han, K. Wang, Z. Hu and C. Chen, Chem. Commun., 2023, 59, 7431 DOI: 10.1039/D3CC01202F

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