Efficient annulation of in situ formed azaoxyallyl cations using a base has been accomplished with diaziridines to provide 1,2,4-triazines at room temperature. The substrate scope, scale up, functional group tolerance and transition-metal free reaction conditions are the important practical features.
P. Karjee, S. Mandal, B. Debnath, N. Namdev and T. Punniyamurthy, Chem. Commun., 2023, 59, 8270 DOI: 10.1039/D3CC02136J
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