A lens-shaped supramolecule based on the bulky pentaphosphaferrocene [CpBIGFe(η5-P5)] and CuBr2

Sebastian Heinl; Eugenia Peresypkina; Werner Kremer; Manfred Scheer

doi:10.1039/D3CC03244B

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A lens-shaped supramolecule based on the bulky pentaphosphaferrocene [Cp^BIGFe(η⁵-P₅)] and CuBr₂†

Sebastian Heinl,^a Eugenia Peresypkina,

^a Werner Kremer^b and Manfred Scheer

*^a

Author affiliations

* Corresponding authors

^a Institute of Inorganic Chemistry, University of Regensburg, Universitätsstraße 31, Regensburg 93040, Germany
E-mail: Manfred.Scheer@ur.de

^b Institute of Biophysics and Physical Biochemistry, University of Regensburg, Universitätsstraße 31, Regensburg 93040, Germany

Abstract

Besides inherent fullerene-like hollow spheres, the metallasupramolecular chemistry of pentaphosphaferrocenes and CuBr₂ afforded a conceptually new product, a compact 3.2 nm sized supramolecule [{1d}₆(CuBr)₃₂(CH₃CN)₆] formed by six largest pentaphosphaferrocene units [Cp^BIGFe(η⁵-P₅)] (1d: Cp^BIG = η⁵-C₅(4-nBuC₆H₄)₅) so far and a framework of 32 copper and 32 bromide ions.

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Article information

DOI: https://doi.org/10.1039/D3CC03244B
Article type: Communication
Submitted: 05 Jul 2023
Accepted: 26 Jul 2023
First published: 26 Jul 2023

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Chem. Commun., 2023,59, 10263-10266

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A lens-shaped supramolecule based on the bulky pentaphosphaferrocene [Cp^BIGFe(η⁵-P₅)] and CuBr₂

S. Heinl, E. Peresypkina, W. Kremer and M. Scheer, Chem. Commun., 2023, 59, 10263 DOI: 10.1039/D3CC03244B

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