Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy

Yijue Xu; Miriam Calabrese; Nicola Demitri; Andrea Pizzi; Tamali Nag; Ivan Hung; Zhehong Gan; Giuseppe Resnati; David L. Bryce

doi:10.1039/D3CC04090A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy†

Yijue Xu,

‡^a Miriam Calabrese,

^b Nicola Demitri,

^c Andrea Pizzi,

^b Tamali Nag,

^d Ivan Hung,

^a Zhehong Gan,

^a Giuseppe Resnati

*^b and David L. Bryce

*^d

Author affiliations

* Corresponding authors

^a National High Magnetic Field Laboratory, Tallahassee, FL 32310, USA

^b Dept. Chemistry, Materials and Chemical Engineering “Giulio Natta”, Politecnico di Milano, Milan, Italy
E-mail: giuseppe.resnati@polimi.it

^c Elettra – Sincrotrone Trieste, Basovizza 34149, Trieste, Italy

^d Dept. of Chemistry and Biomolecular Sci., University of Ottawa, Ottawa, Canada
E-mail: dbryce@uottawa.ca

Abstract

Matere bonds (MaB) to rhenium in a set of organic perrhenates are probed via^185/187Re solid-state NMR in applied magnetic fields of up to 35.2 T, and via^185/187Re NQR. ^185/187Re quadrupolar couplings distinguish between MaB samples and control samples, and their precise values are governed by shear strain of the ReO₄⁻ anions.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D3CC04090A
Article type: Communication
Submitted: 23 Aug 2023
Accepted: 21 Sep 2023
First published: 21 Sep 2023

Download Citation

Chem. Commun., 2023,59, 12609-12612

Author version available

Download author version (PDF)

Permissions

Request permissions

Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy

Y. Xu, M. Calabrese, N. Demitri, A. Pizzi, T. Nag, I. Hung, Z. Gan, G. Resnati and D. L. Bryce, Chem. Commun., 2023, 59, 12609 DOI: 10.1039/D3CC04090A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy†

Abstract

Supplementary files

Article information

Download Citation

Author version available

Permissions

Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy

Social activity

Search articles by author

Spotlight

Advertisements