Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy

Yijue Xu; Miriam Calabrese; Nicola Demitri; Andrea Pizzi; Tamali Nag; Ivan Hung; Zhehong Gan; Giuseppe Resnati; David L. Bryce

doi:10.1039/D3CC04090A

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Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy†

Yijue Xu,

‡^a Miriam Calabrese,

^b Nicola Demitri,

^c Andrea Pizzi,

^b Tamali Nag,

^d Ivan Hung,

^a Zhehong Gan,

^a Giuseppe Resnati

*^b and David L. Bryce

*^d

Author affiliations

* Corresponding authors

^a National High Magnetic Field Laboratory, Tallahassee, FL 32310, USA

^b Dept. Chemistry, Materials and Chemical Engineering “Giulio Natta”, Politecnico di Milano, Milan, Italy
E-mail: giuseppe.resnati@polimi.it

^c Elettra – Sincrotrone Trieste, Basovizza 34149, Trieste, Italy

^d Dept. of Chemistry and Biomolecular Sci., University of Ottawa, Ottawa, Canada
E-mail: dbryce@uottawa.ca

Abstract

Matere bonds (MaB) to rhenium in a set of organic perrhenates are probed via^185/187Re solid-state NMR in applied magnetic fields of up to 35.2 T, and via^185/187Re NQR. ^185/187Re quadrupolar couplings distinguish between MaB samples and control samples, and their precise values are governed by shear strain of the ReO₄⁻ anions.

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Article information

DOI: https://doi.org/10.1039/D3CC04090A
Article type: Communication
Submitted: 23 Aug 2023
Accepted: 21 Sep 2023
First published: 21 Sep 2023

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Chem. Commun., 2023,59, 12609-12612

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Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy

Y. Xu, M. Calabrese, N. Demitri, A. Pizzi, T. Nag, I. Hung, Z. Gan, G. Resnati and D. L. Bryce, Chem. Commun., 2023, 59, 12609 DOI: 10.1039/D3CC04090A

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Chemical Communications

Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy†

Abstract

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Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy

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