Halogen-, oxidant- and directing group-free synthesis of donor–acceptor type conjugated polymers

Sayori Kiyota; Masafumi Hirano

doi:10.1039/D3CC04501C

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Halogen-, oxidant- and directing group-free synthesis of donor–acceptor type conjugated polymers†

Sayori Kiyota

^a and Masafumi Hirano

*^a

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* Corresponding authors

^a Department of Applied Chemistry, Tokyo University of Agriculture and Technology, 2-24-16 Nakacho, Koganei, Tokyo 184-8588, Japan
E-mail: hrc@cc.tuat.ac.jp

Abstract

An intermolecular hydrogen migration from dibutadienylpyridine to dialkynylthiophene catalysed by [Ru(η⁶-naphthalene)(η⁴-oxa-bnd)] (oxa-bnd = 9-oxabicyclo[3.3.1]nona-2,6-diene) produces poly(dialkynylthiophene-alt-dibutadienylpyridine). The exact alternating copolymerisation nature is shown by MALDI-TOF MS.

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DOI: https://doi.org/10.1039/D3CC04501C
Article type: Communication
Submitted: 11 Sep 2023
Accepted: 09 Oct 2023
First published: 18 Oct 2023

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Chem. Commun., 2023,59, 13066-13069

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Halogen-, oxidant- and directing group-free synthesis of donor–acceptor type conjugated polymers

S. Kiyota and M. Hirano, Chem. Commun., 2023, 59, 13066 DOI: 10.1039/D3CC04501C

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Chemical Communications

Halogen-, oxidant- and directing group-free synthesis of donor–acceptor type conjugated polymers†

Abstract

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Halogen-, oxidant- and directing group-free synthesis of donor–acceptor type conjugated polymers

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