Expedient C–H allylation of sulfoxonium ylides: merging C–H and C–C/C–het bond activation†
Sharajit
Saha, 
a
Hemanga
Bhattacharyya,
a
Pallab
Karjee,
a
Bijoy
Debnath,
a
Kshitiz
Verma
a
and
Tharmalingam
Punniyamurthy
*a
a
Hemanga
Bhattacharyya,
a
Pallab
Karjee,
a
Bijoy
Debnath,
a
Kshitiz
Verma
a
and
Tharmalingam
Punniyamurthy
*a
Abstract
Sulfoxonium ylide chelation-assisted C–H allylation of arenes has been accomplished utilizing strained vinyl carbo/heterocycles as the allyl surrogates via sequential C–H and C–C/het bond activation. Broad substrate scope, Co-catalysis, selectivity, and late-stage drug mutation are the important practical features.
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