We show that the incorporation of a biotinylated Co(TAML) cofactor within streptavidin enables asymmetric radical-type oxygen atom transfer catalysis with improved activity and enantioselectivity.
E. J. Meeus, N. V. Igareta, I. Morita, T. R. Ward, B. de Bruin and J. N. H. Reek, Chem. Commun., 2023, 59, 14567 DOI: 10.1039/D3CC04723G
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