Issue 99, 2023
From the journal:

Chemical Communications

Access to isoindole-derived BODIPYs by an aminopalladation cascade†

Heinrich F. von Köller,‡a   Finn J. Geffers,‡b   Pedram Kalvani,a   Adrian Foraita,b   Patrick-Eric J. Loß,b   Burkhard Butschke, ORCID logo c   Peter G. Jonesd  and  Daniel B. Werz ORCID logo *a  

* Corresponding authors

a Albert-Ludwigs-Universität Freiburg, Institute of Organic Chemistry, Albertstraße 21, 79104 Freiburg, Germany
E-mail: daniel.werz@chemie.uni-freiburg.de

b Technische Universität Braunschweig, Institute of Organic Chemistry, Hagenring 30, 38106 Braunschweig, Germany

c Albert-Ludwigs-Universität Freiburg, Institute of Inorganic and Analytical Chemistry, Albertstraße 21, 79104 Freiburg, Germany

d Technische Universität Braunschweig, Institute of Inorganic and Analytical Chemistry, Hagenring 30, 38106 Braunschweig, Germany

Abstract

Here, we present a new route to dyes of the BODIPY family. We first built up a N-Boc-protected dipyrromethene scaffold via an aminopalladation cascade. Subsequentially, the pyrrole moiety was deprotected and the BF2 unit inserted. Depending on the terminating reaction, BODIPYs with either aryl or alkynyl moieties were accessible.

Graphical abstract: Access to isoindole-derived BODIPYs by an aminopalladation cascade

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Article information

DOI
https://doi.org/10.1039/D3CC04913B
Article type
Communication
Submitted
04 Oct 2023
Accepted
13 Nov 2023
First published
13 Nov 2023
This article is Open Access
Creative Commons BY license

Chem. Commun., 2023,59, 14697-14700

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Access to isoindole-derived BODIPYs by an aminopalladation cascade

H. F. von Köller, F. J. Geffers, P. Kalvani, A. Foraita, P. J. Loß, B. Butschke, P. G. Jones and D. B. Werz, Chem. Commun., 2023, 59, 14697 DOI: 10.1039/D3CC04913B

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