FRET mechanism to enhance the quantum yield of the PCz/gC3N4 nanocomposite, an emissive material for OLED applications

Abstract

Conjugated polymers such as polycarbazole (PCz) have captivated more attention than other carbazole-based derivatives due to their superior electrical and optical properties. Accordingly, we synthesized PCz/gC₃N₄ nanocomposites via the in situ polymerization method using FeCl₃ as the oxidative reagent. The synthesized nanocomposites were subjected to characterization techniques to examine their optical and electrical parameters and decide whether the materials were suitable as emissive materials. X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) were carried out to ascertain the crystalline or amorphous nature, surface interactions, and functional groups present in them. The surface microstructural and topographical investigations were conducted using field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (HRTEM) techniques. Optical parameters, such as refractive index ∼2.06, optical absorbance, optical band energy ∼2.77 eV, and the photoluminescence emission range, were studied using UV-Visible and photoluminescence spectrometry. The theoretical relative emission quantum yield of ∼67.9% and 87.7% energy transfer from the donor to the acceptor ion via the Förster energy transfer mechanism are illustrated by the PL data. The Förster energy transfer mechanism has been elaborated. The carrier mobility ∼32.03 m² V⁻¹ S⁻¹, sheet resistance ∼1.6977 × 10² Ω m, carrier density ∼11.96 × 10¹⁴ cm⁻³ and conductivity ∼5.90 × 10⁻³ S cm⁻¹ were computed using Hall effect measurements. The dielectric constant, dielectric loss, and IV characteristic curve were estimated by the LCR and Four-probe IV measurement methods. The high PL emission intensity, CIE coordinates in the blue emission region, and the CCT value indicate that it is a suitable emissive layer material for OLED applications.